This method is little bit complicated. But if you follow the steps, you will find it happening. This process involves two steps - first step is to connect two computers and second is to share the folder.
Step 1: Preparation to Network two computers with crossover cable:
- Make sure both of the computers have NIC card (i.e. Network Interface Card) and Network interface is enabled (to enable Network Interface, go to Start-> Control Panel and click on Network Connections then Right Click on Local Area Connection and click on Enable).
- Make sure you have Cross Over Cable with you (It is different from Straight through Cable and can be available at the same computer store where you get Straight Cable).
- Connect both computers with cross over cable (i.e. connect crossover cable to Ethernet Port of each computers).
Configuration:
You have to assign permanent (Static) IP address. Here are step-by-step instructions showing you how to set permanent IP address and other network information:
- Go to Start and click on Control Panel.
- Control Panel window will appear. Double click on Network Connections.
- Network Connections window will appear. Right click correct Local Area Connection by identifying correct network card and click Properties.
- Select Internet Protocol (TCP/IP) and click on Properties.
- Click on the Network Protocol (TCP/IP) -> Properties and then Click Use the following IP address. After that, enter the values shown below for each of the computer described as computer A and Computer B and then press OK.
Computer A:IP Address: 192.168.100.1
Subnet mask: 255.255.255.0
Gateway: 192.168.100.2
DNS Servers: Leave it blank
Computer B:IP Address: 192.168.100.2
Subnet mask: 255.255.255.0
Gateway: 192.168.100.1
DNS Servers: Leave it blank
Test the connection:
Since your configuration is over so lets test the connectivity between two computers. Click on
Start->Cmd and then Type
ping 192.168.100.2 from Computer A and check to see if you are getting reply or not. It should be like “
Reply from 192.168.100.2: bytes=32 time<1ms ttl="64”.
Step 2: Now Share the file in Computer A:
- Right click on the folder you want to share and click on Sharing and Security.
- Select Share this folder and click OK. You will see hand underneath the folder if it is shared correctly.
(Note: If you don’t see the Share this folder after you click on Sharing and Security, then you have to run Network Setup Wizard. Go to Start->Control Panel and click on Network Setup Wizard. Run the Wizard and enable the Print and File Sharing.)
Search the Shared Folder on Computer A from Computer B:
- Go to Start -> Search -> Click on Computer or People -> Click on Computer on the Network -> Type 192.168.100.1 in Computer Name search Box.
- It will search the computer and display that in the right pane. Click on that and you will see your shared folder in that.
- Now copy your files and folder from that shared folder to Computer B.
Image Source - Crossover cable: Cisco

Links: Do it yourself Ethernet Crossover Cable | Ethernet crossover cable | How To Make a Crossover Cable